Climbing Bean disease?

I sowed Cobra bean seeds as usual in my conservatory (I don't have a greenhouse).  They grew very well, and I put them outside to harden off.  I have just looked at them and the first, large leaves are mottled, and the new ones look shrivelled. Have they got too hot and caught something???  Help!  Any ideas what the problem is, will they recover, can I spray them with something?